Alloy F255 / UNS S32550 / W.Nr. 1.4507

Description

Alloy F255 is a highly alloyed, super duplex (ferrite-austenite) solid solution strengthened alloy, which provides high strength and wear resistance while offering superior corrosion resistance compared to 316 stainless steel. This alloy also offers better resistance to stress corrosion cracking as well as crevice and pitting corrosion than lower alloyed materials. Operating temperatures should be considered when selecting alloy F255 as secondary phases could form within higher temperature ranges. If the alloy is heat treated and allowed to soak between the temperatures of 1000°F and 1800°F, carbides (M23C6), nitrides (M2N) and sigma phase can form. At temperatures approaching 900°F, alpha prime can form. The maximum continuous operating temperature according to ASME Boiler and Pressure Vessel Code, Section VIII is 500°F.

Why alloy F255 is a superior choice in duplex stainless steels
Read our Alloy Insights blog post

Industries & Applications

The combination of strength and wear resistance makes alloy F255 ideal for demanding applications in several different industries, including offshore oil and gas, pulp and paper, nuclear, marine, chemical processing and flue gas desulfurization. Alloy F255 can be a cost effective option for many applications, including oil & gas industry sub-sea equipment, chemical process industry equipment, pollution control scrubbers, marine seals, pumps and valves, bolts and fasteners, grain and vegetable processing equipment, pulp and paper bleaching components, water and sewage treatment and desalination equipment.

Resistance to Corrosion

Compared to typical austenitic alloys such as 304, 316 and 317 stainless steels, alloy F255 displays superior corrosion resistance in most media. Also, alloy F255 typically out performs duplex alloy 2205. Alloy F255 performs well in sulfuric, phosphoric and nitric acids. It also shows excellent resistance to organic acids such as acetic and formic acid. Highly reducing media should be avoided. Pitting resistance equivalent numbers (PREN) are typically used to compare the pitting resistance of various alloys. This number can be calculated from several different equations, which are based on specific alloying elements that contribute to the alloys pitting resistance. For duplex stainless steels the equation typically used to calculate the PREN is as shown below. A word of caution, the PREN is not a guarantee of the corrosion performance of any alloy and should only be used as a guide to help the user select potential alloys for specific use.

PREN = %Cr + (3.3 x %Mo) + (16 x N)

Fabrication and Heat Treatment

Hot and cold forming can be performed on alloy F255 using traditional fabrication methods, although the user must keep in mind that alloy F255 has higher strength properties when compared to 316 stainless steel. Hot working the alloy should be between the temperatures of 1800°F and 2100°F, followed by an annealing heat treatment at 1950°F and water quench. Cold working the alloy to induce more than 10% deformation will require a similar heat treatment. For forming above 20% deformation, intermediate heat treatments should be performed. Machining alloy F255 can be performed using the same methods as traditional stainless steels. Carbide tipped tools are preferred. Stress relieving by heating to 675°F briefly, followed by rapid cooling can be performed on heavily machined components. Welding can be performed by TIG, MIG or SMAW and should be performed on material in the annealed condition. Preheat treatment is not necessary, but it is important to carefully clean the surfaces being welded. If pickling is the desired method for cleaning the surface, a solution with the following composition can be used:

15% HNO˜ + 2% HF (volume by volume) at a minimum temperature of 55°F

Post weld heat treatment is not necessary but preferred when welding heavy sections to optimize corrosion resistance.

Common Trade Names

Ferralium® 255

Ferralium® is a registered trademark of Meighs Ltd, Langley Alloys Division

Chemical Composition (%)

(Fe) Iron Remainder
(Cr) Chromium 24.0 to 27.0
(Ni) Nickel 4.5 to 6.5
(Mo) Molybdenum 2.9 to 3.9
(Cu) Copper 1.5 to 2.5
(Mn) Manganese 1.50 max
(Si) Silicon 1.00 max
(N) Nitrogen 0.10 to 0.25
(P) Phosphorus 0.04 max
(C) Carbon 0.04 max
(S) Sulfur 0.030 max

Applicable Specifications*

Form ASTM ASME
Bar A479 SA479
Plate & Sheet A240 SA240
Seamless & Welded Tube A789 SA789
Seamless & Welded Pipe A790 SA790

* EN10204-3.1 applies to all product forms.

Alloy F255 Frequently Asked Questions

Alloy F255 (UNS S32550) is a super duplex stainless steel with a dual‑phase microstructure consisting of austenite and ferrite. It is engineered to provide significantly higher strength and corrosion resistance than standard duplex and 300‑series stainless steels, particularly in aggressive, chloride‑rich environments. Read our Alloy Insights blog post on Alloy F255 to learn more.

Compared to standard duplex stainless steels such as 2205, Alloy F255 contains higher levels of chromium, molybdenum, and nitrogen, which improve resistance to pitting, crevice corrosion, and stress corrosion cracking. These additions also increase mechanical strength, making F255 better suited for more severe service conditions, including offshore and marine applications.

The addition of copper in Alloy F255 enhances corrosion resistance by helping inhibit the growth of corrosion pits. Copper can redeposit at active pit sites, slowing pit propagation and extending component service life in highly corrosive environments, particularly those involving chlorides.

Yes. Alloy F255 is formulated to reduce susceptibility to sigma phase formation, a brittle intermetallic phase that can form in stainless steels when exposed to temperatures between approximately 1050°F and 1800°F. This improved resistance helps maintain the alloy’s strength, toughness, and corrosion performance during thermal exposure.

Alloy F255 offers substantially higher strength and better corrosion resistance than 300‑series stainless steels, especially in chloride‑induced environments. Its duplex microstructure combines the corrosion resistance and toughness of austenite with the strength of ferrite, allowing for thinner sections, higher pressure ratings, and longer service life in demanding applications.

Alloy F255 is commonly used in marine environments, offshore oil and gas production, and chemical processing facilities where resistance to chloride corrosion is critical. Typical applications include plate, piping, pressure‑bearing components, and structural elements exposed to aggressive seawater or chemical conditions.

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The information shown on this page is intended to be used as a guide and may be revised at any time without prior notice. The information is believed to be reliable and accurate, however Corrosion Materials does not make any warranty or assume any legal liability with respect to the accuracy, completeness or usefulness of the information.